Conductive Iodine‐Doped Red Phosphorus Enabled Dendrite‐Free Lithium Deposition on MXene Matrix

Na, Zhaolin; Li, Wenjing; Li, Lin; Qi, Houkai; Sun, Jing; Lu, Chunlan; Sun, Xudong; Huang, Gang

doi:10.1002/smll.202204341

Cited by 7 publications

(1 citation statement)

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“…Compared with BLK-P, RP is low in cost and toxicity . Recent years, it has been found that RP can be used as a new type of photocatalyst for biomedical applications due to its stable physicochemical properties, suitable bandgap, and the ability to absorb visible light (Figure b). , Pure RP-based photocatalysts have good physicochemical and semiconducting properties, while fast carrier complexation and a small specific surface area lead to low crystallinity and an amorphous nature, limiting reaction sites and ultimately resulting in unsatisfactory photocatalytic effects. , Various nanostructured RP-based photocatalysts have been designed to overcome these drawbacks and improve their photocatalytic activity, providing an effective approach for biomedical applications of RP-based photocatalysts. ,, Nevertheless, RP suffers from a poor distribution of large particles, accumulation of defects, and low crystallinity. This greatly reduces the specific surface area for photocatalytic oxidative reduction.…”

Section: Classifications Of Phosphorus-based Nanomaterialsmentioning

confidence: 99%

Phosphorus-Based Nanomaterials for Biomedical Applications: A Review

Wu,

Xu,

Shao

et al. 2024

ACS Appl. Nano Mater.

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Phosphorus is widely present in living organisms and nature and exists in a variety of isomers with variable crystal structures. There are several common phosphorus monomers in biomedicine, including red phosphorus (RP), black phosphorus (BLK-P), violet phosphorus (VP), and blue phosphorus (BLU-P). Phosphorus-based semiconductor materials (PSCM) have adjustable band gaps, high photogenerated carrier mobility, and efficient photothermal conversion as well as good biocompatibility and degradability. In addition, phosphorus, an essential element for life-sustaining activities, is present in all cells of the human body, accounting for approximately 1% of the body's total weight. Therefore, phosphorus-based nanomaterials have extensive applications in the biomedical field. This review will clarify the classification, preparation methods, physicochemical properties, mechanisms of action, and applications in biomedicine of phosphorus-based nanomaterials while also offering new ideas for their development in biomedicine.

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Section: Classifications Of Phosphorus-based Nanomaterialsmentioning

confidence: 99%

Phosphorus-Based Nanomaterials for Biomedical Applications: A Review

Wu,

Xu,

Shao

et al. 2024

ACS Appl. Nano Mater.

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Opportunities and Challenges of Phosphorus‐based Anodes for Practical Battery Application

She,

Jin,

2024

ChemElectroChem

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Phosphorus‐based anode materials have attracted considerable attention due to their high theoretical capacity, safe operational potential, and favorable redox chemistry for diverse alkali metal‐ion storage applications. Their excellent performance in lithium storage makes them promising candidates for fast‐charging batteries. However, challenges such as complex redox reactions, substantial volume expansion during lithiation, vulnerability to oxidation, and the lack of a mature mass production process hinder their further development. Current research predominantly focuses on establishing multilevel nanostructures or robust solid electrolyte interphases (SEI) to mitigate volume expansion. Nonetheless, a consensus within the academic community on the maximum degree of volume expansion for practical electrode application in cells is yet to be established. Furthermore, investigations into the kinetics of redox reactions, side reactions in the presence of air or electrolyte, and mass production processes for phosphorus‐based anodes are relatively limited. This comprehensive review meticulously examines these challenges, providing nuanced insights. Additionally, the review offers perspectives on potential advancements in phosphorus‐based anode development, contributing to the ongoing discourse on the future trajectory of research in this domain.

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