Abstract:Electromagnetic interference disturbs the working of electronic devices and affects the surroundings and human health. Consequently, research has led to the development of radiation-protection materials. Inherently conducting polymers have been found to be suitable for electromagnetic interference (EMI) shielding owing to their fine electrical conductivity properties. Moreover, nanoparticle-reinforced conjugated polymers have been used to form efficient nanocomposites for EMI shielding. Nanoparticle addition h… Show more
“…It has been found that carbon nanotubes have been employed in super-capacitor electrodes and the CNT-based nanocomposites have mechanical resistance, desirable structure, and high surface area [28,34]. Meanwhile, CNT-based composites show efficient electromagnetic-interference-shielding capacity due to their high magnetism, electrical conductivity, aspect ratio, real/imaginary permittivity, and interfacial polarization [35,36]. Moreover, carbon nanotubes offer excellent electron affinity and transportation performance in some special polymers, which can be applied in bulk to heterojunction solar cells [28].…”
Plastics offer many advantages and are widely used in various fields. Nevertheless, most plastics derived from petroleum are slow to degrade due to their stable polymer structure, posing serious threats to organisms and ecosystems. Thus, developing environmentally friendly and biodegradable plastics is imperative. In this study, biodegradable cellulose/multi-walled carbon nanotube (MCNT) hybrid gels and films with improved ultraviolet-shielding properties were successfully prepared using cotton textile waste as a resource. It was proven that MCNTs can be dispersed evenly in cellulose without any chemical or physical pretreatment. It was found that the contents of MCNTs had obvious effects on the structures and properties of hybrid films. Particularly, the averaged transmittance of cellulose/MCNT composite films in the range of 320–400 nm (T320–400) and 290–320 nm (T290–320) can be as low as 19.91% and 16.09%, when the content of MCNTs was 4.0%, much lower than those of pure cellulose films (T320–400: 84.12% and T290–320: 80.03%). Meanwhile, the water contact angles of the cellulose/MCNT films were increased by increasing the content of MCNTs. Most importantly, the mechanical performance of cellulose/MCNT films could be controlled by the additives of glycerol and MCNTs. The tensile strength of the cellulose/MCNT films was able to reach as high as 20.58 MPa, while the elongation at break was about 31.35%. To summarize, transparent cellulose/MCNT composites with enhanced ultraviolet-shielding properties can be manufactured successfully from low-cost cotton textile waste, which is beneficial not only in terms of environmental protection, but also the utilization of natural resources.
“…It has been found that carbon nanotubes have been employed in super-capacitor electrodes and the CNT-based nanocomposites have mechanical resistance, desirable structure, and high surface area [28,34]. Meanwhile, CNT-based composites show efficient electromagnetic-interference-shielding capacity due to their high magnetism, electrical conductivity, aspect ratio, real/imaginary permittivity, and interfacial polarization [35,36]. Moreover, carbon nanotubes offer excellent electron affinity and transportation performance in some special polymers, which can be applied in bulk to heterojunction solar cells [28].…”
Plastics offer many advantages and are widely used in various fields. Nevertheless, most plastics derived from petroleum are slow to degrade due to their stable polymer structure, posing serious threats to organisms and ecosystems. Thus, developing environmentally friendly and biodegradable plastics is imperative. In this study, biodegradable cellulose/multi-walled carbon nanotube (MCNT) hybrid gels and films with improved ultraviolet-shielding properties were successfully prepared using cotton textile waste as a resource. It was proven that MCNTs can be dispersed evenly in cellulose without any chemical or physical pretreatment. It was found that the contents of MCNTs had obvious effects on the structures and properties of hybrid films. Particularly, the averaged transmittance of cellulose/MCNT composite films in the range of 320–400 nm (T320–400) and 290–320 nm (T290–320) can be as low as 19.91% and 16.09%, when the content of MCNTs was 4.0%, much lower than those of pure cellulose films (T320–400: 84.12% and T290–320: 80.03%). Meanwhile, the water contact angles of the cellulose/MCNT films were increased by increasing the content of MCNTs. Most importantly, the mechanical performance of cellulose/MCNT films could be controlled by the additives of glycerol and MCNTs. The tensile strength of the cellulose/MCNT films was able to reach as high as 20.58 MPa, while the elongation at break was about 31.35%. To summarize, transparent cellulose/MCNT composites with enhanced ultraviolet-shielding properties can be manufactured successfully from low-cost cotton textile waste, which is beneficial not only in terms of environmental protection, but also the utilization of natural resources.
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