1971
DOI: 10.1021/j100906a014
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Conductance of tetraalkylammonium halides in ethylene glycol

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1972
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Cited by 12 publications
(11 citation statements)
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“…17 These were earlier discussed in the introduction. There are also reports where the deviation from reciprocal dependence between self-diffusivity of the solute and 55 whereas for water(H 2 O) and ethylene glycol (EG) from Ueno et al 44 and Sieno et al, 51 respectively. All λ 0 values of Li + and Cl − in the above solvents except in water, acetonitrile, methanol, and EG are taken from the Krumgalz.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…17 These were earlier discussed in the introduction. There are also reports where the deviation from reciprocal dependence between self-diffusivity of the solute and 55 whereas for water(H 2 O) and ethylene glycol (EG) from Ueno et al 44 and Sieno et al, 51 respectively. All λ 0 values of Li + and Cl − in the above solvents except in water, acetonitrile, methanol, and EG are taken from the Krumgalz.…”
Section: Resultsmentioning
confidence: 99%
“…Plot of limiting ion conductivity (λ 0 ) versus viscosity for (a) Li + and (b) and Cl – ion in different solvents at 25 °C. The viscosity data of acetone, acetonitrile (AN), methanol (MeOH), nitromethane (NM), dimethylformamide (DMF), pyridine (Pyd), dimethylacetamide (DMA), ethanol (EtOH), N -methylformamide (NMF), dimethylsulfoxide (DMSO), propylene carbonate (PC), and formamide (FA) are taken from Krumgalz whereas for water(H 2 O) and ethylene glycol (EG) from Ueno et al and Sieno et al, respectively. All λ 0 values of Li + and Cl – in the above solvents except in water, acetonitrile, methanol, and EG are taken from the Krumgalz .…”
Section: Resultsmentioning
confidence: 99%
“…It should be mentioned that the glycol in the later study26 possessed a viscosity 4% lower than that generally accepted; this affects the extrapolation slightly (as does the choice of a lower dielectric constant) and suggests that some water may have been introduced into the solvent from the ion-exchange column t^iat was employed. 25 Several other studies contain useful information. The conductances of four electrolytes over a range of glycol-water mixtures have been graphically reported26 and discussed,27 and Erdey-Grúz has kindly sent us28 the detailed results.…”
Section: Discussionmentioning
confidence: 99%
“…A Further Description of Complete Equilibrium Constants1 by William L. Marshall Reactor Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830 (Received November 25,1970) Publication costs assisted by the Oak Ridge National Laboratory, U. S. Atomic Energy Commission A complete equilibrium constant (K°), in which solvent species are included to reduce the number of parameters needed for describing solute ionization equilibria, is derived from a multistep solvation treatment of a conventional ionization constant (K). The previously assumed net change (k) in the number of solvent molecules in the reaction process is shown to have this mathematical form for both single and multiple solvent systems.…”
Section: Introductionmentioning
confidence: 99%
“…On the basis of the conventional transport theory, it has been suggested that the parameter To is the controlling variable in the composition dependence of transport at low temperatures. To reflects the cohesive forces in liquids, and in the case of charge unsymmetrical salt systems,28 the cohesive energy of one component (1) may be much less than that of the other (2). In other words Thd « Tq<2) and, therefore, one can presume a linear relation between T0 ami composition.…”
Section: Resultsmentioning
confidence: 99%