Pure nitrogen dioxide
(NO
2
) has significant economic
value and is widely used in many fields, for which condensation technology
plays an important role in separation and purification. However, developing
cost-effective NO
2
condensers remains challenging due to
the lack of precise theoretical guidelines and comprehensive understanding
of NO
2
condensation process. In this work, NO
2
condensation at various inlet surface subcoolings, mole fractions
of noncondensable gas (NCG), and
Re
numbers was studied
with a visualization experimental system. The influential rules of
each parameter on heat transfer coefficients (HTCs) and the NO
2
condensate state as the coexistence of droplet, streamlet
and film were revealed. A substantial underestimation of experimental
data by the classical heat and mass transfer analogy (HMTA) model
was quantified. The large discrepancy was found to originate from
the uniqueness in heat transfer, mass transfer, and condensate state
caused by NO
2
dimerization during condensation. A modified
HMTA model was developed considering the release heat of dimerization
reaction and the promotion of mass transfer by an increased NO
2
concentration gradient within the diffusion layer which contribute
to improvements of HTCs by ∼6 and ∼49%, respectively.
The correction of liquid film roughness regarding potential heterogeneity
of dimerization was proposed as a function of the key parameters,
contributing to the improvement of HTCs by ∼150%. An accurate
theoretical formula for HTCs prediction within an error of ±25%
was finally derived, providing the key step for success in practical
applications.