Abstract:In this work we concentrate on the quantification of the sticking coefficient of CD 3 + on fusion relevant plasma-sprayed tungsten (PSW) surfaces in the collision energy range from about 0 up to 100 eV. PSW samples were cut from ASDEX Upgrade tiles and both untreated and electropolished surfaces are investigated. A collision energy, E coll , selected CD 3 + ion beam deposits hydrocarbon layers onto the target surfaces which are ex-situ analysed by Nuclear Reaction Analysis (NRA) via D( 3 He,p) 4 He at 800 kV and 2.5 MeV, respectively. The sticking coefficient, S, for deuterium has been found to be collision energy dependent, decreasing with increasing energy. It is in the order of S~0.4 for PSW and S0.1 for electro polished PSW at E coll = 10 eV. Secondary ion mass spectra of charged particles are recorded after ion-surface collisions with the polished PSW surface for collision energies up to 100 eV. While at very low collision energies below about 10 eV only simple reflection of CD 3 + is observed, at higher collision energies both fragmentation of the projectile and fragmentation of ion-surface reaction products are observed. Concerning the stability of the layers we prove that hydrogen exchange plays a role on the time scale of weeks.