2008
DOI: 10.1016/j.cplett.2008.09.034
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Concentration profile within diffusion layer under non-forced hydrodynamic conditions measured by Michelson interferometer

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Cited by 18 publications
(5 citation statements)
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“…55 With the decrease of the diffusion energy barrier, the atomic diffusion becomes easy accordingly, thus the morphology changes from fractal to dendrite and eventually the predicted polyhedral shapes, matching very well with experimental data. In the synthesis of colloid metal nanocrystals, most of the precursors are metal ions in solution, so the concentration gradient, 64 reduction rate 65 and diffusion 57 all have important effects on the growth.…”
Section: Diffusion-limited Growthmentioning
confidence: 99%
“…55 With the decrease of the diffusion energy barrier, the atomic diffusion becomes easy accordingly, thus the morphology changes from fractal to dendrite and eventually the predicted polyhedral shapes, matching very well with experimental data. In the synthesis of colloid metal nanocrystals, most of the precursors are metal ions in solution, so the concentration gradient, 64 reduction rate 65 and diffusion 57 all have important effects on the growth.…”
Section: Diffusion-limited Growthmentioning
confidence: 99%
“…Electrochemical method Some complex structures can be formed on the electrode by designing the proper potential and concentration of electrolytes or other parameters using theory from the electric double layer model. [64][65][66][67] Hierarchical morphologies includ-ing noble metal wire, [50] flower, [51] and nanoparticles on some templates can be obtained.…”
Section: Redox Reactionmentioning
confidence: 99%
“…The hierarchical morphology of deposited noble-metal nanostructures is usually determined by the following factors: limited diffusion of metal ions near the electrode, concentration field and electric field near the electrode, and limited diffusion of metal atoms on the disposition crystalline plane. The concentration of metal ions near the tips of the hierarchical nanostructure is higher, which induced the protuberant growth . The electric field would limit the diffusion of metal ions and directed the growth of nanostructures along the electric field directions. , To further understand the influence factors of the growth of Au nanostructures, different electrodeposition parameters were investigated, including deposition potential, and concentrations of HCl and HAuCl 4 .…”
Section: Resultsmentioning
confidence: 99%