Computer simulation of defects in ammonium perchlorate

Goldstein, Mark; Keenan, A. G.

doi:10.1016/0022-4596(73)90135-7

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Materials With Chains Of Hydrogen Bonds Broken By Intramolec...1

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1975

1978

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Cited by 5 publications

(1 citation statement)

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“…A theoretical analysis of the electrical conductivity of ammonium perchlorate has recently appeared. 464 The model used was that of polarizable point ions, and was investigated by a computer simulation technique. The ions considered were NH4+ and CI04-, and no account was taken of the possible formation of protons.…”

Section: Materials With Chains Of Hydrogen Bonds Broken By Intramolec...mentioning

confidence: 99%

Proton conduction and injection in solids

Glasser¹

1975

Chem. Rev.

277

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Section: Materials With Chains Of Hydrogen Bonds Broken By Intramolec...mentioning

confidence: 99%

Proton conduction and injection in solids

Glasser¹

1975

Chem. Rev.

277

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Effect of manganese dioxide on the thermal decomposition of ammonium perchlorate

Kishore¹,

Verneker²,

Sunitha³

1977

J. Biochem. Toxicol.

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Thermal decomposition of powdered ammonium perchlorate, catalysed by manganese dioxide (MnOz), has been studied in the low concentration ranges of the catalyst. MnOz sensitises the thermal decomposition of ammonium perchlorate. The activation energy estimations of catalysed ammonium perchlorate show that the value is about 30 kcal/mol throughout the low and the high temperature regions whereas uncatalysed ammonium perchlorate gives two activation energies, 20 kcal/mol in the low temperature region (280-320°C) and 60 kcal/mol in the higher temperature region (350-390°C). This behaviour has been explained on the basis of an electron transfer process. The effectiveness of MnOz in the thermal decomposition further increases on pre-heating the sample at 50°C for two weeks; manganese ions enter the ammonium perchlorate lattice during the process of pre-heating.

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Effect of manganese dioxide on the thermal decomposition of ammonium perchlorate

1977

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Thermal decomposition of powdered ammonium perchlorate, catalysed by manganese dioxide (MnO2), has been studied in the low concentration ranges of the catalyst. MnO2 sensitises the thermal decomposition of ammonium perchlorate. The activation energy estimations of catalysed ammonium perchlorate show that the value is about 30 kcal/mol throughout the low and the high temperature regions whereas uncatalysed ammonium perchlorate gives two activation energies, 20 kcal/mol in the low temperature region (280–320°C) and 60 kcal/mol in the higher temperature region (350–390°C). This behaviour has been explained on the basis of an electron transfer process. The effectiveness of MnO2 in the thermal decomposition further increases on pre‐heating the sample at 50°C for two weeks; manganese ions enter the ammonium perchlorate lattice during the process of pre‐heating.

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Computer simulation of defects in ammonium perchlorate

Cited by 5 publications

References 20 publications

Proton conduction and injection in solids

Proton conduction and injection in solids

Effect of manganese dioxide on the thermal decomposition of ammonium perchlorate

Effect of manganese dioxide on the thermal decomposition of ammonium perchlorate

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