Abstract:Using reaction model systems (nitroso oxide ArNOO, Ar
= Me2NC6H4 or O2NC6H4; exhaustive set of methyl- and cyano-substituted
ethylenes),
a detailed study of the reaction mechanism of ArNOO with unsaturated
compounds was carried out using the density functional theory (M06L/6311
+ G(d,p)). The reaction is preceded by the formation of a reagent
complex of stacking type, which is favorable for further transformation.
Depending on the structure of alkene, the reaction may proceed via two extreme mechanisms: synch… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.