A doping series of AlAs (001) quantum wells with Si δ-modulation doping on both sides reveals different dark and post-illumination saturation densities, as well as temperature dependent photoconductivity. The lower dark two-dimensional electron density saturation is explained assuming deep binding energy of ∆DK = 65.2 meV for Si-donors in the dark. Persistent photoconductivity (PPC) is observed upon illumination, with higher saturation density indicating shallow post-illumination donor binding energy. The photoconductivity is thermally activated, with 4 K illumination requiring post-illumination annealing to T = 30 K to saturate the PPC. Dark and post-illumination doping efficiencies are reported.PACS numbers: 73.20.b,73.21.fg,73.50.Pz,73.43.f,71.18.+y Two dimensional electron systems (2DESs) in aluminum arsenide (AlAs) quantum wells (QWs) are interesting for their valley degeneracy and heavy mass 1,2,3 . The valley index quantum number acts as an extra pseudospin degree of freedom, and the heavy mass allows interactions to play a larger role at a given density 4 . Recently progress has also been made in fabricating and characterizing one-dimensional AlAs nanostructures 5,6,7 . Although improvements in high mobility AlAs 2DES structures have been reported 8,9 , many important material parameters such as the donor binding energy and doping efficiency have been obscured by substrate charge effects 10 . Since these parameters are instrumental in designing and optimizing heterostructures, we have performed a systematic study on double-sided-doped quantum wells which screen away unwelcome substrate effects. In the process, we also identify a thermally activated persistent photoconductivity (PPC) not previously reported.AlAs is an indirect band gap III-V semiconductor with three degenerate conduction band valleys at the X-points of the Brillouin zone edge. In (001) growth, the biaxial strain between AlAs and Al x Ga 1−x As (x = 0.45) decreases the energy of the two in-plane valleys such that for wide wells W > 55Å, 11,12 only these two valleys are degenerately occupied. In AlAs, the longitudinal and transverse electron masses are anisotropic, m l = 1.1 m e and m t = 0.2 m e , respectively 3 , and the effective Landé g-factor g * = 2 (Ref. 11).Free electrons in AlAs/AlGaAs heterostructures come from two different sources: intentional Si-dopant and un-