This paper presents the results of the measurement of polonium, uranium and plutonium alpha radio-nuclides in seawater and biota of the southern Baltic ecosystem as well as the recognition of their accumulation processes in the trophic chain. Investigation of the polonium 21~ and plutonium 239+ 24Opu concentrations in Baltic biota revealed that these radionuclides are strongly accumulated by some species. Mean values of the bioconcentration factor (BCF) fell within the range 9.102 to 3.7.104 . The Baltic Sea algae, benthic animals and fish concentrated uranium radioisotopes only to a small extent and mean BCF values for this element range from 1 to 55, which is several orders of magnitude lower than that for polonium and plutonium. Moreover, it was found that Baltic fish constitute an important source of polonium 21~ for humans.
IntroductionPolonium was the first element discovered by Maria Sklodowska-Curie when studying pichblende radioactivity from Joachimsthal, Bohemia [1,2]. Polonium is very rare natural element, uranium ores contain only about 100 ~tg of the element per ton [3]. Thirty seven radioisotopes (with isomers) of polonium are known, with atomic masses ranging from 192 to 218 but only seven from them are naturally occurring isotopes [4]. 21~ is the most important natural isotope of polonium. It belongs to the natural uranium 23SU decay series but its fate depends on further members of this series, viz. radium 2a6Ra, and most of all on lead 21~ Radon 222Rn is emitted from of Earth's surface and constitutes the general source of atmospheric 219po [5]. The total amount of airborne polonium 21~ depends directly on the amount of lead 21~ supplied and formed in the atmosphere [6,7]. Close to 4,3 EBq of radon 222Rn is being released from the earth surface every year, from which about 25.5 PBq of the lead isotope 21~ is formed. Apart from polonium 21~ formed by the decay of lead 21~ in the atmosphere, additional amounts are emitted directly from the surface ocean (0.52 PBq) and Earth surface, as a result of forest fires [8] and volcanic eruption [9,10]. The atmosphere also contains a small amount of artificial 21~ and 21~ originating from nuclear weapons and nuclear facilities which are located in the stratosphere. For example, the activity of artificial lead 21~ originating from nuclear weapons in 1962 was estimated to 33 PBq [11]. Polonium 21~ which occurs in the air is precipitated within dry atmospheric fallout, rain and snow, then deposited on the surface of land and oceans. Atmospheric deposition of 21~ lies within a broad range from 5 to 250 MBq m 2 yr 1 [12]. Atmospheric precipitation of 21~ and, to a smaller extent, precipitation of 21~ itself on the surface of seas and oceans are the basic sources of polonium 21~ entering the marine environment. A small amount of 21~ is formed in situ as a result of the radioactive decay of uranium 23Su contained in seawater.