Zoned tourmaline (schorl-dravite) in the matrix of hydrothermal explosive breccia and ore veins in gold deposits, Chita region, Eastern Transbaikalia, Russia, are associated with Na-and K-rich porphyry-type subvolcanic intrusives. d 18 O values of tourmaline from three gold deposits (Darasun, Talatui, Teremkinskoye) are þ8.3&, þ7.6&, and þ6.0& and calculated d 18 O values of fluids responsible for the tourmalinization are þ7.3&, þ7.7&, and þ4.2&, respectively. These data imply an igneous fluid source, except at the Teremkin deposit where mixing with meteoric water is indicated. Wide ranges of Fe 3þ /Fe tot and the presence of vacancies characterize the Darasun deposit tourmaline indicating wide ranges of f (O 2 ) and pH of mineralizing fluids. Initial stage tourmalines from the gold deposits of the Darasun ore district are dravite or high mg schorl. Second stage tourmaline is characterized by oscillatory zoning but with Fe generally increasing towards crystal rims indicating decreasing temperature. Third
GEOSCIENCE FRONTIERSjournal homepage: www.elsevier.com/locate/gsf GEOSCIENCE FRONTIERS 3(1) (2012) 59e71 stage tourmaline formed unzoned crystals with x Mg (mole fraction of Mg) close to that of the first stage tourmaline, due to a close association with pyrite and arsenopyrite. From Fe 3þ /Fe tot values, chemical composition and crystallization temperatures, logf(O 2 ) of mineralizing fluids ranged from ca. À25 to À20, much higher than for the gold-bearing beresiteelistvenite association, indicating that tourmalinization was not related to gold mineralization. ª 2011, China University of Geosciences (Beijing) and Peking University. Production and hosting by Elsevier B.V. All rights reserved.