Composite polymer electrolytes based on the low crosslinked copolymer of linear and hyperbranched polyurethanes

Hong, Ling; Shi, Liyi

doi:10.1002/app.26064

Cited by 1 publication

(3 citation statements)

References 52 publications

(53 reference statements)

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“…79 The ionic conductivities and thermal characteristics of composite polymer electrolytes made of PU-based polymer and LiClO 4 were explored using a low crosslinked copolymer of linear and hyperbranched polyurethane (CHPU). 95 According to the FTIR and Raman spectra, the PU copolymer could dissolve more lithium salt than the similar polymer electrolytes of the noncrosslinked hyperbranched PU, thus exhibiting greater conductivity. At 25 °C, the electrolyte CHPU30-LiClO 4 obtained its maximum conductivity of 1.51105 S cm −1 at a salt concentration with ethylene number/Li + ratio of 4.…”

Section: Crosslinked Polyurethane Polymer Matrixmentioning

confidence: 99%

“…At 25 °C, the electrolyte CHPU30-LiClO 4 obtained its maximum conductivity of 1.51105 S cm −1 at a salt concentration with ethylene number/Li + ratio of 4. 95 Crosslinking is a promising strategy for improving the mechanical strength of a polymer electrolyte, in addition to reducing PEO crystallization and providing high temperature dimensional stability. Also, crosslinked polymer can absorb more lithium salt compared to the non-crosslinked polymer and hence increases the conductivity value.…”

Section: Crosslinked Polyurethane Polymer Matrixmentioning

confidence: 99%

“…According to the FTIR and Raman spectra, the PU copolymer could dissolve more lithium salt than the similar polymer electrolytes of the non‐crosslinked hyperbranched PU, thus exhibiting greater conductivity. At 25 °C, the electrolyte CHPU30‐LiClO 4 obtained its maximum conductivity of 1.51105 S cm −1 at a salt concentration with ethylene number/Li + ratio of 4 95 …”

Section: Approachesmentioning

confidence: 99%

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Polyurethane‐based polymer electrolyte for lithium ion batteries: a review

Misenan

Khiar

Eren

2022

Polymer International

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For the past decade, lithium ion batteries have dominated the high‐performance and mobile markets. Despite their domination in many sectors, the development of contemporary commercial lithium ion batteries is hampered by safety concerns such as leakage, burning and even explosions caused by organic liquid electrolytes with low boiling points. Polymer electrolytes are a promising option to solve or mitigate these issues. Polymer electrolytes have the advantages of low flammability, good flexibility, excellent thermal stability and high safety. Among others, polyurethane (PU) has attracted attention as a promising polymer electrolyte candidate for the future. The soft and hard segments of the polymeric chain given by polyols and isocyanates, respectively, give PU its characteristic multiphase structure. The PU's soft segment can operate as a polymeric solvent to solvate the cations, while the hard segment can be functionalized to retain a wider range of electrochemical stability, allowing the construction of polymer electrolytes in electrochemical devices. Numerous researchers have concentrated on developing high‐performance PU‐based polymer lithium ion batteries. Nonetheless, low lithium ion conductivity characteristics remain the most significant obstacles to its commercialization. In order to tackle the issues and improve the overall performance, both physical and chemical modifications are widely investigated to form a PU‐based polymer electrolyte. In the light of this work, this review discusses PU as a polymer host and the approaches to increase its ionic conductivity, including polymer blending, copolymerization, crosslinking, filler addition, plasticization, salt dopant addition as well as the integration of PUs into polymeric ionic liquids. In this review, previous work regarding PU‐based polymer electrolytes from 1988 to 2021 is discussed and summarized. © 2022 Society of Industrial Chemistry.

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Section: Crosslinked Polyurethane Polymer Matrixmentioning

confidence: 99%

Section: Crosslinked Polyurethane Polymer Matrixmentioning

confidence: 99%

Section: Approachesmentioning

confidence: 99%

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