Complexes of aziridine with nickel(II) chloride

Root, Charles A.; Allison, Juanita W.

doi:10.1021/ic50094a036

Cited by 7 publications

(2 citation statements)

References 2 publications

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“…Aziridine Complexes in Which the Aziridine Ring is Intact. Central atoms which have been used for complexes in which the aziridine ring is intact include U (293), Ti (294-296), Zr (296), Cr (288)(289)(290)(291)(292)(293)(294)(295)(296)(297)(298)(299), Mo (299), Wo (299), Mn (298-300), Fe (301), Co (297,298,300,(302)(303)(304), Rh (305,306), Ni (298,300,303,307), Pd (297,298), Pt (297,298,(308)(309)(310), Cu (298,300), Ag (300, 311), Zn (300,311,312), Cd (300,311), and Hg (300). The metals Rh and Pt in low oxidation states form stable and inert aziridine complexes (313,314).…”

Section: Reactions With Transition-metal Compoundsmentioning

confidence: 99%

Imines, Cyclic

Scherr¹,

Steuerle²,

Fikentscher³

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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Section: Reactions With Transition-metal Compoundsmentioning

confidence: 99%

Imines, Cyclic

Scherr¹,

Steuerle²,

Fikentscher³

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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“…26 However, many aziridine complexes of a variety of transition metals with up to four aziridine ligands are currently known, most of which have been published by us. [27][28][29][30][31][32][33][34][35][36][37][38][39][40][41] Ring opening reactions especially with functionalized metal carbonyls have also been reported, e.g. with hydrido carbonyl complexes to form β-aminoacyl complexes via M-C addition [42][43][44][45][46] or with halogenido carbonyl complexes to form five-membered aminooxycarbene complexes.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, structural characterization, antimicrobial and cytotoxic effects of aziridine, 2-aminoethylaziridine and azirine complexes of copper(ii) and palladium(ii)

et al. 2012

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Reaktionen von Metallcarbonylen mit Aziridin

1973

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Die Hexacarbonyle von Chrom, Molybdan und Wolfram setzen sich photochemisch oder thermisch mit Aziridin (in) zu Komplexcn M(CO)fj-,in, (n = I, 2, 3) um. Aus den cis-Bis(aziridin)tctracarbonylmetall-Verbindungen entstehen in Gegcnwart von protischen Losungsmittelii durch Reaktion zwischen zwei Aziridinliganden Tetracarbonylkomplexe M(C0)ddiin mit dem N-(2-Aminoathyl)aziridin-Chelatligandcn (dun). Aus Tc-CH3C-HdMn(C0)3 und in bzw. diin werdeii die Verbindungen x-CH3C:~H~Mn(CO)~in bzw. (x-CH3CsH4)-(CO)2Mn~-diin-Mn(CO)2(n-CH+Z5H4) erhalten. Die Struktur-und Bindungsverhaltnisse in diesen Komplexcri werden an Hand der IR-Spektren diskutiert. Reactions of Metal Carbonyls with AziridineThe photochemical or thermal reaction of the hexacarbonyls of chromium, molybdenum, and tungsten with aziridine (in) yields the complexes M(CO)6-ninn (n -1, 2, 3). From the cisbis(aziridin)tetracarbonylmetal compounds in the presence of protic solvents chelate complexes M(C0j4diin with N-(2-aminoethyl)aziridine (diin) as ligdnd, formed by rcaction of two aziridine ligands, have been obtained. The preparation of n-CH3CsFI1Mn(CO)zin and of (Tc-CH3C5H4)(C0)2Mn-diin-Mn(CO)2(sr-CH3CSF14) is rcported. The structure and bonding of these complexes arc discussed on the basis of the i. r. spectra. Mit Aziridin sind bereits eine Reihe von kationischen Metallkomplexenz) desTyps [M(in),Im I (M z. B. = Ag 1, Ni2+; in = Aziridin) bekannt. Vor kurzeni untersuchten Fritz und Hierl3) auf Grund von IR-und NMR-Messungen die Bindungsverhaltnisse in diesen Komplexen. Bei der Wmsetzung von Pentacarbonyl(methoxy-methy1carben)chrom mit Isonitrilen bildet sich ein Carbenkomplex mit ALiridinstruktur". Octacarbonyldikobalt setd sich mit Aziridin unter Valenzdisproportionierung des Metalls zu [Coins] [Co(CO)4]2 urns). Vor kurzem berichteten wir uber die Reaktion von Carbonylmetallhydriden mit Ariridin, die unter Ringoffnung des Aziridins zu /3-Aminopropionylchelat-Komplexen fiihrt 1). Wir untersuchten nun die Umsetzungen von Aziridin mit verschiedenen neutralen Metallcarbonylen. 1 ) 2. Mitteil. Uber Reaktionen +on Metallkomplexen mil gespannten Ringsystcmen; 1.

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Complexes of aziridine with nickel(II) chloride

Cited by 7 publications

References 2 publications

Imines, Cyclic

Imines, Cyclic

Synthesis, structural characterization, antimicrobial and cytotoxic effects of aziridine, 2-aminoethylaziridine and azirine complexes of copper(ii) and palladium(ii)

Reaktionen von Metallcarbonylen mit Aziridin

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