Complexes Containing the Nitrate Ion

Addison, C. C.; Sutton, D.

doi:10.1002/9780470166093.ch4

Cited by 52 publications

(11 citation statements)

References 232 publications

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“…In agreement with published literature, 39,40 it was found that the decomposition does not occur at standard conditions because the reaction requires a Gibbs free energy (ΔG) of 71.9 kcal mol −1 to form sodium monoxide (NaO) and nitrogen monoxide (NO) according to reaction 4:…”

supporting

confidence: 89%

“…In agreement with published literature [39][40] , it was found that the decomposition does not occur at standard conditions because the reaction requires a Gibbs free energy (G) of 71.9…”

Section: Decomposition Of Pure Nano2supporting

confidence: 76%

“…According to Sutton and Addison 39 , NaNO2 may be considered as a stable substance since the decomposition takes place much above the melting point at high temperature (between 400°C and 600°C). Here, in the commonly accepted decomposition mechanism 39 , a metal nitrite decomposes to form nitrogen and the corresponding metal oxide.…”

Section: Decomposition Of Pure Nano2mentioning

confidence: 99%

“…Here, in the commonly accepted decomposition mechanism 39 , a metal nitrite decomposes to form nitrogen and the corresponding metal oxide.…”

Section: Decomposition Of Pure Nano2mentioning

confidence: 99%

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Theoretical and Experimental Study of the Reaction between Ammonium Nitrate and Sodium Salts

Cagnina

Rotureau

Singh

et al. 2016

Ind. Eng. Chem. Res.

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Hazards posed by chemical incompatibility, especially in a large-scale industrial environment, warrant a deeper understanding of the mechanisms of the reactions involved in these phenomena. In this study, reactions between ammonium nitrate and two sodium salts, namely, sodium nitrate and sodium nitrite, have been studied by ab initio calculations (with density functional theory, DFT) and experimental calorimetric methods (with differential scanning calorimetry, DSC, and heat flux calorimetry, HFC). The agreement between theoretical and experimental results allows an understanding of the thermal decomposition behaviors of the two sodium salts when exposed to ammonium nitrate. Moreover, this study highlighted the critical role of the water that appears to promote the incompatibility between ammonium nitrate and sodium nitrite.

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supporting

confidence: 89%

Section: Decomposition Of Pure Nano2supporting

confidence: 76%

Section: Decomposition Of Pure Nano2mentioning

confidence: 99%

“…Here, in the commonly accepted decomposition mechanism 39 , a metal nitrite decomposes to form nitrogen and the corresponding metal oxide.…”

Section: Decomposition Of Pure Nano2mentioning

confidence: 99%

See 2 more Smart Citations

Theoretical and Experimental Study of the Reaction between Ammonium Nitrate and Sodium Salts

Cagnina

Rotureau

Singh

et al. 2016

Ind. Eng. Chem. Res.

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“…These bands are assigned as 1 , 2 , 3 , 4 , 5 and 6 modes, respectively and their frequencies are consistent with those associated with terminally bonded monodendate nitrato group [28,29]. In addition to these, two weak bands with a separation of ca.…”

Section: Infrared Spectra and Mode Of Bondingmentioning

confidence: 87%

Characterization, kinetics of thermal decomposition and molecular modeling studies on mercury (II) complexes of biologically active glutathione

Singh

Sharma

Garg

2005

Main Group Chemistry

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Mercury (II) complexes of reduced glutathione (GSH) of general composition [Hg(L)(X)]H 2 O, SCN 7 , CH 3 CO 2 7 , Cl 7 ) have been synthesized and characterized by elemental analysis, infrared spectra and electronic spectral studies. The stability constant of the mercury complex has been evaluated potentiometrically, and thermogravimetric (TG) and differential thermal analytical (DTA) studies have also been carried out for these complexes. Infrared spectra indicate deprotonation and coordination of cysteinyl sulfur with the metal ions. It indicates the presence of water molecules in all the complexes which has been supported by TG and DTA studies. The thermal behavior of complexes shows that the water molecule is removed in first step, followed by the removal of anions and then decomposition of the ligand molecule in subsequent steps. General mechanisms describing the decomposition of the solid complexes are suggested. Kinetic and thermodynamic parameters were computed from the thermal decomposition data. The geometry of the metal complexes has been optimized with the help of molecular modeling.

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Structures and Properties of HX ₂ ‐ and HXY‐ Anions

Tuck

1967

Progress in Inorganic Chemistry

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Complexes Containing the Nitrate Ion

Cited by 52 publications

References 232 publications

Theoretical and Experimental Study of the Reaction between Ammonium Nitrate and Sodium Salts

Theoretical and Experimental Study of the Reaction between Ammonium Nitrate and Sodium Salts

Characterization, kinetics of thermal decomposition and molecular modeling studies on mercury (II) complexes of biologically active glutathione

Structures and Properties of HX ₂ ‐ and HXY‐ Anions

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Complexes Containing the Nitrate Ion

Cited by 52 publications

References 232 publications

Theoretical and Experimental Study of the Reaction between Ammonium Nitrate and Sodium Salts

Theoretical and Experimental Study of the Reaction between Ammonium Nitrate and Sodium Salts

Characterization, kinetics of thermal decomposition and molecular modeling studies on mercury (II) complexes of biologically active glutathione

Structures and Properties of HX 2 ‐ and HXY‐ Anions

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Product

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Structures and Properties of HX ₂ ‐ and HXY‐ Anions