Complexes amines du rhodium(I)

Ferrocenyl-nitrogen donor ligands. Synthesis and characterization of rhodium(I) complexes of ferrocenylpyridine and related ligands

“…Chromatography solvents were of analytical grade and used without purification, with the exception of dichloromethane and hexane which were of chemically pure grade and distilled in air prior to use. [17], ferrocenyldiphenylphosphine [26], dichlorotetracarbonyldirhodium [27], dicarbonylchloro(pyridine)rhodium [28], bis(carbonyl)chloro(4-aminopyridine)dicarbonylchlororhodium [29], chloro(1, 5-cyclooctadiene)rhodium(I) dimer [30], chloro(1,5-cyclooctadiene)(pyridine)rhodium [31], (1,5-cyclooctadiene)-bis(pyridine)rhodium hexafluorophosphate [32] and (1, 5-cyclooctadiene)bis(pyridine)rhodium perchlorate [32]. 1 0 , 2 0 ,3 0 ,4 0 ,5 0 -Pentamethylazaferrocene was prepared according to the method of Fu [33] and obtained courtesy of Dr. P. Beagley, Organometallic Research Group, University of Cape Town.…”

Cationic rhodium(I) sulfoxide complexes. Synthesis and spectroscopic properties

“…Facile cleavage (8)(9)(10)(11)(12) (1 3, 14). The removal of chloride as a silver salt from 4 facilitates the coordination of acetone, a weak and easily displaced ligand (15); reactions 1 and 2.…”