Complex formation of halogen substituted tetraphenylporphyrins and Cd(II)-tetraphenylporphyrins with MnCl2 in DMF
S. V Zvezdina,
N. V Chizhova,
N. Z Mamardashvili
Abstract:Reactions of complex formation of 5,10,15,20-tetra-(2,6-dichlorophenyl)porphyrin, 5,10,15,20-tetra-(2,6-difluorophenyl)porphyrin and metal exchange of their cadmium complexes with manganese chloride(II) in dimethylformamide were investigated. ortho -Substituted manganese complexes were synthesized by prolonged refluxing of the corresponding porphyrins with an excess of MnCl2 in dimethylformamide. Using the metal exchange reaction of Cd(II)-5,10,15,20-tetra-(2,6-dichlorophenyl)porphyrin and Cd(II)-5,10,15,20-te… Show more
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