with my co-authors, I would like to thank the three anonymous reviewers who provided useful comments and suggestions. Chapter 7 is derived from a paper co-authored with Gianluca Orsatti, Davide Consoli and Francesco Quatraro, titled "Public procurement, local labour markets and green technological change: Evidence from US Commuting Zones". I would like to thank them for taking on board a non-economist and introducing him to the world of econometrics. This paper was in the process of revision and resubmission to Environmental and Resource Economics when this thesis was completed. Chapter 5 and 6 are based on papers co-authored with Davide Consoli and Nicolò Barbieri. The first one is titled "Specialisation, diversification and the ladder of green technology" and has been submitted to Research Policy, the second one "Specialization, diversification and environmental technology life-cycle" is under review for Economic Geography. Both papers and this dissertation would not have been possible without the contribution and dedication of Davide and Nicolò, to whom I would like to reiterate my heartfelt gratitude. v