Competitive pathways for the oxalate substitution reaction of the (glycinato-N,O)bis(oxalato)chromate(III) ion

Kallen, Thomas W.; Hamm, Randall E.

doi:10.1021/ic50198a021

Cited by 7 publications

(1 citation statement)

References 6 publications

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“…The solution was concentrated to ca. 5 mL and cooled at -20 °C overnight. White crystals of triphenylphosphine were removed, and the mother liquor was further concentrated to about half the volume and cooled.…”

mentioning

confidence: 99%

Preparation, characterization, and properties of platinum(0) complexes with tri-n-butyl phosphite, tri-n-butylarsine, and tri-n-butylstibine

Goldsworthy¹,

Hartley²,

Marshall³

et al. 1985

Inorg. Chem.

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= 600 Hz). IR: 1512 (s), 1440 (s), 1355 (w), 1301 (w), 1282 (s), 1209 (m), 1169 (w), 1154 (w), 1096 (w), 1076 (w), 1006 (w), 969 (w), 921 (w), 874 (s), 852 (w), 829 (m), 784 (w), 647 (w), 496 (w), 438 (w) cm"1.Preparation of [Mo(Ntol)(S2CNEt2)2]20. A portion of PPh3 (0.128 g; 0.49 mmol) was added to a stirred solution of MoO(Ntol)(S2CNEt2)2 (0.500 g; 0.97 mmol) in CH2C12 (25 mL) at room temperature. After 12 h, the violet solution was taken to dryness, and the purple residue was triturated with Et20 (3 X 25 mL), collected by filtration, and dried in vacuo. Analysis of the Et20 washings by IR and 31P NMR spectroscopy revealed the presence of Ph3PO. Elemental analysis of the purple product indicates that the dimeric complex is obtained as the CH2C12 solvate.

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confidence: 99%

Preparation, characterization, and properties of platinum(0) complexes with tri-n-butyl phosphite, tri-n-butylarsine, and tri-n-butylstibine

Goldsworthy¹,

Hartley²,

Marshall³

et al. 1985

Inorg. Chem.

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ChemInform Abstract: COMPETITIVE PATHWAYS FOR THE OXALATE SUBSTITUTION REACTION OF THE (GLYCINATO‐N,O)BIS(OXALATO)CHROMATE(III) ION

KALLEN,

HAMM

1979

Chemischer Informationsdienst

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Substitution Reactions of Inert Metal Complexes—Coordination Numbers 6 and Above

Twigg¹

1983

Volume 1: Mechanisms of Inorganic and Organometallic Reactions

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Competitive pathways for the oxalate substitution reaction of the (glycinato-N,O)bis(oxalato)chromate(III) ion

Abstract: Die Kinetik und der Mechanismus der Reaktion des Titelions (I) mit Oxalsäure in KNO3‐, NaNO3‐ und NaClO4‐haltigem Medium der Ionenstärke 1.00 M im Temp.‐Bereich von 44.4 ‐ 55.8°C werden untersucht.

Cited by 7 publications

References 6 publications

Preparation, characterization, and properties of platinum(0) complexes with tri-n-butyl phosphite, tri-n-butylarsine, and tri-n-butylstibine

Preparation, characterization, and properties of platinum(0) complexes with tri-n-butyl phosphite, tri-n-butylarsine, and tri-n-butylstibine

ChemInform Abstract: COMPETITIVE PATHWAYS FOR THE OXALATE SUBSTITUTION REACTION OF THE (GLYCINATO‐N,O)BIS(OXALATO)CHROMATE(III) ION

Substitution Reactions of Inert Metal Complexes—Coordination Numbers 6 and Above

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