Competing base-promoted E2 and E1 reactions of an acidic tertiary substrateElectronic supplementary information (ESI) available: the effect of base concentration on rate constant and product composition. See http://www.rsc.org/suppdata/p2/b2/b200758d/

Zeng, Xiaofeng; Thibblin, Alf

doi:10.1039/b200758d

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Elimination Reactions1

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2003

2009

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“…18b As part of a continuing study of solvolysis reactions Zeng and Thibblin looked at the competing processes of base-promoted E1 and E2 reactions of a tertiary substrate 4-chloro-4-(4Ј-nitrophenyl)pentan-2-one 30. 19 The solvolysis of 30 in aqueous acetonitrile yields the alcohol. 20 Leaving-group fluorine and secondary deuterium multiple kinetic isotope effects (KIEs) were determined.…”

Section: Elimination Reactionsmentioning

confidence: 99%