2012
DOI: 10.1016/j.ceramint.2012.05.015
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Comparison of the superconducting properties of Cu0.5Tl0.5Ba2Ca2(Cu3−yZny)O10−δ prepared at different synthesis temperatures

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“…To investigate any possible spin occurrence of Cu atoms in the conducting plane, we doped spin-less Zn 2+ (3d 10 ) atoms at the Cu site in the CuO 2 planes of Cu 0.5 Tl 0.5 Ba 2 Ca 2 (Cu 3-y Zn y )O 10-δ and Cu 0.5 Tl 0.5 Ba 2 Ca 3 (Cu 4-y Zn y )O 12-δ superconductors. 8,9 These compounds have demonstrated superconductivity of up to 87% after the replacement of Cu by Zn at the copper site. When CuO 2 planes are completely substituted by ZnO 2 planes in these compounds, the superconductivity disappears and the material becomes a semiconductor.…”
Section: Introductionmentioning
confidence: 99%
“…To investigate any possible spin occurrence of Cu atoms in the conducting plane, we doped spin-less Zn 2+ (3d 10 ) atoms at the Cu site in the CuO 2 planes of Cu 0.5 Tl 0.5 Ba 2 Ca 2 (Cu 3-y Zn y )O 10-δ and Cu 0.5 Tl 0.5 Ba 2 Ca 3 (Cu 4-y Zn y )O 12-δ superconductors. 8,9 These compounds have demonstrated superconductivity of up to 87% after the replacement of Cu by Zn at the copper site. When CuO 2 planes are completely substituted by ZnO 2 planes in these compounds, the superconductivity disappears and the material becomes a semiconductor.…”
Section: Introductionmentioning
confidence: 99%