“…Achieving high-quality, dimensionally accurate castings that exhibit smooth surfaces and are devoid of pinhole defects necessitates the use of suitable binder system enabling: (i) a high level of structural integrity of moulds and cores through adequate strength and thermo-mechanical stability of composite dimensions [8,9] upon exposure to high-temperature and dynamic and static pressures [2] exerted by molten metal in mould cavities, (ii) the fast-speed and low-cost fabrication of moulds and cores, (iii) minimal gaseous byproduct formation and kinetics during the binder and residual moisture decomposition [9][10][11][12][13], (iv) adequate composite permeability enabling the rapid evacuation of gaseous byproducts evolving in mould cavity upon exposure to liquid metal at the initial stages of its flow and solidification, whilst simultaneously preventing molten metal ingress into inherently porous composite structures, (v) low fracture energy of composites (moulding sand), essential for good mould/core system 'collapsibility' (shakeout) during casting removal and cleaning [2] and (vi) the absence of sintered sand residues adhering to the surface of casting. Geometrical aspects of particulate-filled composites morphology controlling their interior 3-D structure and functional properties: engineering composites in comparison with permeable moulding sand composites: (a) typical engineering composite comprising: (i) particulate filler compacted to achieve the maximum achievable packing density of reinforcing material (74%) according to face-centred cubic (FCC) packing (or hexagonal closest packing; HCP) manner [3] and (ii) polymeric matrix material (binder: 26%) completely filling all porous cavities between compacted particles; (b) FCC-packed permeable composite material (74% filler) with individual filler particles coated by very thin, continuous binder film, as typically observed in moulding sands bonded with liquid organic [1,2,4,5] or inorganic binders [6,7]; (c) inter-particle pendular bridges connecting individual filler particles (an example of an FCC-packed permeable composite filled with uniform diameter spherical particles); this is an optimum structure of moulding sand composite facilitating maximisation of composite strength whilst minimising the binder contents; (d) inter-particle pendular bridges between filler particles: a permeable composite with cubic lattice compacting, achieving packing density of 52.36% [3].…”