2018
DOI: 10.5155/eurjchem.9.3.228-235.1728
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Comparison of the leaving groups during the study of the aquation of halopentaammine cobalt(III) complex in tartarate at different percentage of tert-butanol

Abstract: The experimental kinetic study of aquation for both complexes bromopentaammine cobalt(III) and chloropentaammine cobalt(III) ions in the presence of tartarate solution in mixed solvent media of water with tert-butanol (10-50%, v:v) was examined spectrophotometrically at different temperatures (30-60 °C) by comparing the special effects of the leaving group of chloro and bromo on the rate constant of aquation. Comparison of kip (rate constant of ion-pairing) for both complexes and show the non-linear plots of l… Show more

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