Comparison of the co-ordinative behaviour of calcium(II) and magnesium(II) from crystallographic data

Synthesis, physicochemical and pharmacokinetic characterization of calcium uronates

“…This metal ion has a flexible coordination sphere and CN between 6 and 8 are the most popular [43][44][45].…”

Solvent‐Induced Pore‐Size Adjustment in the Metal‐Organic Framework [Mg3(ndc)3(dmf)4] (ndc = naphthalenedicarboxylate)

“…Additionally, the coordination chemistry of magnesium is less flexible than that of zinc, and octahedral complexes are often found. [6] In the case of polyfunctional ligands used for the synthesis of Mgbased MOFs, competitive coordination by water or other solvent ligands may result in low-dimensional network topologies or isolated complexes, and thus porosity cannot be expected. However, the first magnesium-based metal-organic framework with permanent porosity and accessibility for very small molecules (H 2 , O 2 ) was recently reported by Dinća and Long.…”

Magnesium sulphate complexes with hexamethylenetetramine and 1,10-phenanthroline

“…The coordination chemistry and biochemical binding mechanisms of a magnesium ion Mg 2? are of special interest due to its significant role in biological processes [6][7][8][9]. For instance, at molecular level, these metal ions participate in homeostasis and are important in electrolyte pathophysiology [10].…”