1989
DOI: 10.1029/wr025i010p02205
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Comparison of soil freezing curve and soil water curve data for Windsor sandy loam

Abstract: Unfrozen water content as a function of temperature was measured in the laboratory using pulsed nuclear magnetic resonance (PNMR) for a Windsor sandy loam soil. The PNMR data were related to previously measured soil moisture retention data through the modified Clausius‐Clapeyron equation, with suitable adjustment for surface tension. The transformed measured unfrozen water content data and the previously measured soil moisture retention data were expressed by a Brooks and Corey type of equation with the requir… Show more

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Cited by 117 publications
(73 citation statements)
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“…Many researchers have developed freezing characteristic functions through analogies with water retention models developed to describe the drying and wetting of unsaturated unfrozen soils, where gas and liquid phases coexist in the pores (e.g. Koopmans & Miller, 1966;Miller, 1978;Black & Tice, 1989;Grant & Sletten, 2002;Coussy, 2005). The different pressures between the liquid water and ice phases expressed by the Clausius-Clapeyron equation (equation (4)) suggest that surface tension forces should develop along the interface between the two phases, as illustrated in Fig.…”
Section: Freezing Characteristic Functionmentioning
confidence: 99%
“…Many researchers have developed freezing characteristic functions through analogies with water retention models developed to describe the drying and wetting of unsaturated unfrozen soils, where gas and liquid phases coexist in the pores (e.g. Koopmans & Miller, 1966;Miller, 1978;Black & Tice, 1989;Grant & Sletten, 2002;Coussy, 2005). The different pressures between the liquid water and ice phases expressed by the Clausius-Clapeyron equation (equation (4)) suggest that surface tension forces should develop along the interface between the two phases, as illustrated in Fig.…”
Section: Freezing Characteristic Functionmentioning
confidence: 99%
“…If the water in drying soil were mainly retained by capillary forces (equation (5)), equation (16) would have to be modified by multiplying by s/s sl , because of the different free energies of the ice-water and air-water interfaces [Koopmans and Miller, 1966;Black and Tice, 1989]. In the capillary bundle model, only larger capillary tubes contain ice when the temperature is near 0°C.…”
Section: Soil Freezing Characteristic Curvementioning
confidence: 99%
“…volume of liquid phase/volume of pore) to the porous medium thermodynamic properties [20]. Many researchers have developed freezing characteristic functions through analogies with water retention models developed to describe the drying and wetting of unsaturated unfrozen soils, where gas and liquid phases coexist in the pores [24][25][26][27][28]. The different pressures between the liquid water and ice phases expressed by the Clausius-Clapeyron Eq.…”
Section: Freezing Characteristic Functionmentioning
confidence: 99%