“…The heterogeneity and anisotropy of pore structures are involved in the CPC; thus, the CPC has been applied to a wide range of natural or synthetic porous media, such as shale, tight sandstone, carbonate rock, packing bed, coal rock, cement slurry, and fine sediment containing natural gas hydrate (Cai et al, ; Lei & Santamarina, ; Sang et al, ; Voigt et al, ; Wyrzykowski et al, ). From the equivalent hydraulic size distribution of the pore‐throat (SDPT) given by the CPC, many critical pore structure parameters, such as the threshold pressure and radius, the maximum displacement pressure P d and its corresponding maximum pore‐throat radius r max , the average pore‐throat radius r mean , the irreducible water saturation S wir , the structural coefficient T , and the pore‐throat radius at any saturation (e.g., r 15 , r 25 , r 50 ), can be directly determined (Nooruddin et al, ). Recently, Nishiyama and Yokoyama () reported that the critical radius from the CPC is the radius of the largest sphere that can move freely in porous media.…”