Comparison of OH(A–X) chemiluminescence spectra from photo-initiated intra-cluster reaction of HBr–N2O isomers prepared with He and Ar seeding gases

Okano, Akinori; Ohoyama, Hiroshi; Kasai, Toshio

doi:10.1016/s0009-2614(03)00644-4

Cited by 4 publications

(1 citation statement)

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“…15 Concerning chemical reactions in N 2 OÁM complexes (M = HBr, HI), 16,17 evidence of OH formation has been found for the photo-initiated reaction in HBrÁN 2 O van der Waals clusters. 18,19 The authors discuss two stable isomeric structures which result in two different reaction mechanisms.…”

Section: Introductionmentioning

confidence: 99%

The weakly-bound complex Cl·N2O studied by high resolution photodetachment photoelectron spectroscopy

Boesl

Distelrath

Selzle

2008

Phys. Chem. Chem. Phys.

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Zero kinetic energy photoelectron spectroscopy of the weakly bound complex Cl(-).N(2)O is presented. Adiabatic detachment energies between the anionic complex and the neutral complex states X(1/2), I(3/2), and II(1/2) as well as frequencies of van der Waals modes are supplied. Supported by theoretical simulations, these results correlate with a T-shaped structure of the anionic and an L-shaped structure of the neutral molecular complex. The weakly bound neutral complex Cl.N(2)O has been discussed as a prereactive state of the chemical reaction Cl + N(2)O --> ClO + N(2) [A. Lesar, M. Hodoscek, M. Senegacnik, J. Chem. Phys. 1996, 105, 917].

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Section: Introductionmentioning

confidence: 99%

The weakly-bound complex Cl·N2O studied by high resolution photodetachment photoelectron spectroscopy

Boesl

Distelrath

Selzle

2008

Phys. Chem. Chem. Phys.

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New aspects of UV photolysis of hydrogen peroxide. Nitrogen matrix isolation FTIR and theoretical studies

Krupa

Wierzejewska

2016

Journal of Photochemistry and Photobiology A: Chemistry

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Orienting and aligning molecules for stereochemistry and photodynamics

Aquilanti

Bartolomei

Pirani

et al. 2005

Phys. Chem. Chem. Phys.

124

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Production, characterization and control of polarization states of molecules (specifically, alignment and/or orientation) are of importance for investigating in detail the stereodynamics of elementary processes involving elastic, inelastic and reactive events and also to prepare targets for selective photodynamical investigations. The focus here is on those molecular beam techniques which show perspectives in the applications offering appealing features for "duty cycle" and intensity characteristics. After a review of the basic experimental advances, mainly obtained in the last ten years, the attention will be addressed to recent studies carried out on the collisional alignment of hydrocarbon molecules and on orientation of symmetric top molecules by exploiting honeycomb hexapole fields. The first case is a prototype of "natural" polarization techniques, the second one of those where polarization is "forced" by external fields.

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Comparison of OH(A–X) chemiluminescence spectra from photo-initiated intra-cluster reaction of HBr–N2O isomers prepared with He and Ar seeding gases

Cited by 4 publications

References 20 publications

The weakly-bound complex Cl·N2O studied by high resolution photodetachment photoelectron spectroscopy

The weakly-bound complex Cl·N2O studied by high resolution photodetachment photoelectron spectroscopy

New aspects of UV photolysis of hydrogen peroxide. Nitrogen matrix isolation FTIR and theoretical studies

Orienting and aligning molecules for stereochemistry and photodynamics

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