The resistivity, Seebeck coefficients, and power factors of as‐prepared RBaCo2O5+δ (R112) ceramics with variable R3+ ion sizes were investigated systemically. The resistivity of Pr112 and Nd112 exhibits semimetal behavior, which is different with other R112 who have a semiconductor‐semimetal transition. At room temperature, Dy112 has the biggest Seebeck coefficient. While at higher temperature, Y112 has best thermoelectric power. In addition, the affects of normalizing temperature on the transport properties of Eu112 ceramic were investigated. Its power factor above room temperature is improved by normalizing, and an optimum normalizing temperature exists at 400°C.