2014
DOI: 10.3390/polym6072037
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Comparison of in Situ and ex Situ Methods for Synthesis of Two-Photon Polymerization Polymer Nanocomposites

Abstract: Abstract:This article reports about nanocomposites, which refractive index is tuned by adding TiO 2 nanoparticles. We compare in situ/ex situ preparation of nanocomposites. Preparation procedure is described, properties of nanocomposites are compared, and especially we examine the applicability of two-photon polymerization (2PP) of synthesized nanocomposites. All prepared samples exhibit suitable optical transparency at specific laser wavelengths. Three-dimensional structures were generated by means of two-pho… Show more

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Cited by 142 publications
(64 citation statements)
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“…The new generation materials, including hybrid materials, can be produced by in-situ ( Fig.1) and ex-situ (Fig.2) methods. [2] In accordance with the recommendation of the International Union of Pure and Applied Chemistry -IUPAC. We define the materials as follows [ [1].…”
Section: Introductionmentioning
confidence: 94%
“…The new generation materials, including hybrid materials, can be produced by in-situ ( Fig.1) and ex-situ (Fig.2) methods. [2] In accordance with the recommendation of the International Union of Pure and Applied Chemistry -IUPAC. We define the materials as follows [ [1].…”
Section: Introductionmentioning
confidence: 94%
“…The high resolution and high degree of design flexibility conferred by 2PP means that it can be applied to different microfluidic applications in which liquid fluids need to be transported, mixed, or controlled by means of valves or switches 2 . Furthermore, by using photosensitive resins that contain the appropriate nanomaterials, different functions can be incorporated into the 2PP-fabricated microstructure 3,4 . For example, one could potentially make the microstructure electrically conductive, or have a refractive index that varies as a function of position, or make the microstructure chemically functionalized.…”
Section: Introductionmentioning
confidence: 99%
“…Material limitations due to the need of low viscosity resins and relatively high cost of the equipment (up to half a million dollars) are the main drawbacks of the TPP technique. Guo et al [22] studied the use of TPP technique for the fabrication of periodic 3D scaffold using poly(aryl ether sulfone) filled with titanium oxide. The nanocomposites showed a sufficiently high optical transparency, which allowed the successful fabrication of the scaffold.…”
mentioning
confidence: 99%