Comparative study on molecular associations in solid and liquid phases of aqueous solutions. III. Topoenergetic considerations on electric conductivity in electrolyte solutions

Abstract

The composite structure of electrolyte soluiions previously revealed by four measuring systems is studied new by measurements of electric conductance in standard experimental conditions. Two phylogenic series of solutions were considered, namely, ionic salts/water and HCl/(organic solvent + water), for which the deviation of the corrected specific conductance of the solution in respect to the solvent and the solute concentration are the eigcnvalue and the governing potential, respectively, for a correct topoenergetic retrieval of data. The results of ontogenic and phylogenic data show that ionic compounds catalyze the polymerization of water molecules while polar organic solvents segregate these molecular associations towards a critical value of their concentration.VergZeichende Untersuchung der rnolekuzaren Assoziationen in festen und fliissigen Phasen voia wiifirigen LBsungen.