Abstract:Significant advances in fused deposition modeling (FDM), as well as its myriad applications, have led to its growing prominence among additive manufacturing (AM) technologies. When the technology was first developed, it was used for rapid prototyping to examine and analyze a product in the design stage. FDM facilitates rapid production, requires inexpensive tools, and can fabricate complex-shaped parts; it, therefore, became popular and its use widespread. However, various FDM processing parameters have proven… Show more
“…They also provide sufficient strength to the final objects, giving them versatility, too [ 43 ]. The scientific literature reports a mechanical resistance, in terms of tensile strength, between 1.5 MPa and 150 MPa [ 41 , 45 , 48 , 49 , 53 , 57 ].…”
Section: Materials For Fff Technologymentioning
confidence: 99%
“…The most common and commercially available FFF filaments are the acrylonitrile butadiene styrene (ABS) and the polylactic acid (PLA) [ 45 , 58 ]. ABS and PLA possess thermal (melting point, glass transition temperature, etc.)…”
Section: Materials For Fff Technologymentioning
confidence: 99%
“…It is not biodegradable, and it is extruded at high temperatures (around 220–280 °C). The literature reports the following mechanical properties for ABS: tensile strength between 13.0 to 65.0 MPa, Young’s modulus between 1.00 to 2.65 GPa, and flexural strength equal to 66 MPa [ 45 , 46 , 49 , 57 ]. ABS is widely used in industry, due to its impact resistance and toughness, for example for prototyping, production of toys and components for boats and cars.…”
Recently, Fused Filament Fabrication (FFF), one of the most encouraging additive manufacturing (AM) techniques, has fascinated great attention. Although FFF is growing into a manufacturing device with considerable technological and material innovations, there still is a challenge to convert FFF-printed prototypes into functional objects for industrial applications. Polymer components manufactured by FFF process possess, in fact, low and anisotropic mechanical properties, compared to the same parts, obtained by using traditional building methods. The poor mechanical properties of the FFF-printed objects could be attributed to the weak interlayer bond interface that develops during the layer deposition process and to the commercial thermoplastic materials used. In order to increase the final properties of the 3D printed models, several polymer-based composites and nanocomposites have been proposed for FFF process. However, even if the mechanical properties greatly increase, these materials are not all biodegradable. Consequently, their waste disposal represents an important issue that needs an urgent solution. Several scientific researchers have therefore moved towards the development of natural or recyclable materials for FFF techniques. This review details current progress on innovative green materials for FFF, referring to all kinds of possible industrial applications, and in particular to the field of Cultural Heritage.
“…They also provide sufficient strength to the final objects, giving them versatility, too [ 43 ]. The scientific literature reports a mechanical resistance, in terms of tensile strength, between 1.5 MPa and 150 MPa [ 41 , 45 , 48 , 49 , 53 , 57 ].…”
Section: Materials For Fff Technologymentioning
confidence: 99%
“…The most common and commercially available FFF filaments are the acrylonitrile butadiene styrene (ABS) and the polylactic acid (PLA) [ 45 , 58 ]. ABS and PLA possess thermal (melting point, glass transition temperature, etc.)…”
Section: Materials For Fff Technologymentioning
confidence: 99%
“…It is not biodegradable, and it is extruded at high temperatures (around 220–280 °C). The literature reports the following mechanical properties for ABS: tensile strength between 13.0 to 65.0 MPa, Young’s modulus between 1.00 to 2.65 GPa, and flexural strength equal to 66 MPa [ 45 , 46 , 49 , 57 ]. ABS is widely used in industry, due to its impact resistance and toughness, for example for prototyping, production of toys and components for boats and cars.…”
Recently, Fused Filament Fabrication (FFF), one of the most encouraging additive manufacturing (AM) techniques, has fascinated great attention. Although FFF is growing into a manufacturing device with considerable technological and material innovations, there still is a challenge to convert FFF-printed prototypes into functional objects for industrial applications. Polymer components manufactured by FFF process possess, in fact, low and anisotropic mechanical properties, compared to the same parts, obtained by using traditional building methods. The poor mechanical properties of the FFF-printed objects could be attributed to the weak interlayer bond interface that develops during the layer deposition process and to the commercial thermoplastic materials used. In order to increase the final properties of the 3D printed models, several polymer-based composites and nanocomposites have been proposed for FFF process. However, even if the mechanical properties greatly increase, these materials are not all biodegradable. Consequently, their waste disposal represents an important issue that needs an urgent solution. Several scientific researchers have therefore moved towards the development of natural or recyclable materials for FFF techniques. This review details current progress on innovative green materials for FFF, referring to all kinds of possible industrial applications, and in particular to the field of Cultural Heritage.
“…The samples were fabricated with a Prusa i3 MK3S (Prusa Research, Prague, Czech Republic) model 3D printer, employing the FDM technology. The fabricated samples were PETG possesses good chemical resistance, durability, and excellent formability for 3D printing [42][43][44][45]. PETG can be easily vacuumed and pressure-formed, as well as heat-bent, thanks to its low forming temperatures.…”
The porosity and inhomogeneity of 3D printed polymer samples were examined using terahertz time-domain spectroscopy, and the effects of 3D printer settings were analysed. A set of PETG samples were 3D printed by systematically varying the printer parameters, including layer thickness, nozzle diameter, filament (line) thickness, extrusion, and printing pattern. Their effective refractive indices and loss coefficients were measured and compared with those of solid PETG. Porosity was calculated from the refractive index. A diffraction feature was observed in the loss spectrum of all 3D printed samples and was used as an indication of inhomogeneity. A “sweet spot” of printer settings was found, where porosity and inhomogeneity were minimised.
“…Their chemical stability, electrical conductivity, and surface area are all good [15][16][17]. Polymer composites have attracted a lot of interest because they provide novel combinations with superior properties to the individual components [18][19][20][21][22].…”
Polypyrrole/multiwalled carbon nanotubes composites (PPy/MWCNTs) were produced in an acidic solution utilizing an in situ oxidative polymerization method using ferric chloride as an oxidizing agent and sodium dodecyl sulfate as a soft template. Thermal evaporation was used to fabricate thin films from polypyrrole/multiwalled carbon nanotube composites. The resulting composites were examined by different techniques to explore their morphology, structural and electrical characteristics. The surface morphology analysis revealed that polypyrrole structure is a two-dimensional film with impeded nanoparticles and the thickness of coated PPy around the MWCNTs decreases when increasing the amount of MWCNTs. XRD analysis revealed that the average crystallite size of the prepared composites is 62.26 nm. The direct energy gap for PPy is affected by a factor ranging from 2.41 eV to 1.47 eV depending on the contents of MWCNTs. The thin film’s optical properties were examined using experimental and TDDFT-DFT/DMOl3 simulation techniques. The optical constants and optical conductivity of the composites were calculated and correlated. The structural and optical characteristics of the simulated nanocomposites as single isolated molecules accord well with the experimental results. The nanocomposite thin films demonstrated promising results, making them a viable candidate for polymer solar cell demands. Under optimal circumstances, the constructed planar heterojunction solar cells with a 75 ± 3 nm layer of PPy/MWCNTs had a power conversion efficiency (PCE) of 6.86%.
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