“…Methanol, the simplest aliphatic alcohol, are produced over hundreds of million-tons-scale every year from syngas, natural gas, coal, biomass, the distillation of wood, and also photo/ electrocatalytic CO 2 reduction. [8][9][10][11][12][13] Under the background of carbon neutrality, the industrial synthesis technology of methanol with catalytic reduction of carbon dioxide as raw material has been developed rapidly, realizing the low cost of methanol production. Owing to its low cost, low toxicity, and easy activation, methanol has been considered to be a sustainable C/H/O carrier and platform chemical that widely used as fuel, solvent, the cheapest hydrogen energy storage molecule, the feedstock for manufacture of bulk chemicals such as formaldehyde, acetic acid, methyl esters, methylamines, dimethyl ether, and lower olefins.…”