Comonomer sequence assignment of the 13C n.m.r. spectra of some poly(epichlorohydrin) derivaties obtained by nucleophilic substitution

Pérez, Mónica; Ronda, Juan C.; Reina, José Antonio; Serra, Àngels

doi:10.1016/s0032-3861(97)10125-2

Cited by 12 publications

(6 citation statements)

References 14 publications

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“…The analysis of this product by 1 H and 13 C NMR does not show signals attributable to CH 2 OH groups, but the presence of oxy-1methylenethylene units was confirmed by the characteristic signals at 3.9 and 4.2 ppm in the 1 H NMR spectrum and at 84 ppm in 13 C NMR spectrum. [50,51]…”

Section: Resultsmentioning

confidence: 99%

Synthesis of New Reactive Polyethers: Poly(-bromoalkyl-1-glycidylether)s

Montornés¹,

Reina²,

Ronda³

2001

Macromol. Chem. Phys.

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Section: Resultsmentioning

confidence: 99%

Synthesis of New Reactive Polyethers: Poly(-bromoalkyl-1-glycidylether)s

Montornés¹,

Reina²,

Ronda³

2001

Macromol. Chem. Phys.

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“…These polymers obtained after chemical modification, either by substitution reactions [17], elimination [18], reduction [19], oxidation [20], alkylation [21], or grafting [22],…”

Section: Introductionmentioning

confidence: 99%

Theoretical and Experimental Study of the Chemical Modification of Poly(epichlorohydrin) by Grafting Menthol

Hadjadj Aoul,

Adda,

Sebba

et al. 2023

Ecsoc 2023

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“…Chloromethane group is beneficial specially usable because being easily modified through a replacement reaction with several nucleophilic reactants under normal conditions [6]. Therefore, polymers containing chlorine are appropriate initial materials for synthesis of polymers with novel functional groups [7]. Polymers containing chloromethyl units are suitable for synthesis of functional polymers [8].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Investigation of the New Derivatives of Poly(Epichlorohydrin) Containing Energetic Groups

Atabaki

Keshavarz

Bastam

2017

Propellants Explo Pyrotec

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In this research, poly(epichlorohydrin)(PECH) is modified by phenylhydrazine as well as 4-nitrophenylhydrazine and 2,4-dinitro phenylhydrazine. The chemical structures of the new derivatives of PECH are analyzed by Fourier transform infrared (FT-IR), nuclear magnetic resonance (NMR) and ultraviolet-visible (UV) techniques as well as carbon-hydrogen-nitrogen (CHN) ultimate analysis. Thermal characteristics of reaction products are studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Moreover, glass transition temperature (T g ) of these new polymers are determined. The results indicate that modifications of the poly(epichlorohydrin) are carried out successfully. The new energetic derivatives of PECH are good candidates for chemical industries, which may be considered as a novel class of energetic binders.Keywords: PECH · phenyl hydrazine · 4-nitrophenylhydrazine · 2,4-dinitrophenylhydrazine · energetic poly(epichlorohydrin) 2 Experimental MaterialsAll the chemicals used in this work were of analytical grade. Epichlorohydrin and N,N-dimethylacetamide (DMAc) were purchased from sigma-Aldrich. Tin tetrachloride (SnCl 4 ), phenylhydrazine, 4-nitrophenylhydrazine, 2,4-dinitrophenylhydrazine, ethylene glycol and dichloromethane were obtained from [a] F.

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Comonomer sequence assignment of the 13C n.m.r. spectra of some poly(epichlorohydrin) derivaties obtained by nucleophilic substitution

Cited by 12 publications

References 14 publications

Synthesis of New Reactive Polyethers: Poly(-bromoalkyl-1-glycidylether)s

Synthesis of New Reactive Polyethers: Poly(-bromoalkyl-1-glycidylether)s

Theoretical and Experimental Study of the Chemical Modification of Poly(epichlorohydrin) by Grafting Menthol

Synthesis and Investigation of the New Derivatives of Poly(Epichlorohydrin) Containing Energetic Groups

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