Common and less-common coordination modes of the typical chelating and heteroaromatic ligands

Гарновский, А. Д.; Sadimenko, Alexander P.; Sadimenko, M. I.; Гарновский, Д. А.

doi:10.1016/s0010-8545(98)00084-8

Cited by 68 publications

(53 citation statements)

References 304 publications

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“…Molecular complexes of azoles 12, azines 13 and their derivatives 14-17 are of high interest at present [5,13,14,22]. In these complexes, metal cycles with distinct number of bonds were observed; among them, 5-or 6-member rings are the most stable, for example 18-22 [10,15].…”

Section: Ementioning

confidence: 99%

“…Cr(CO) 3 Cene complexes 31 (especially ferrocene 31, M=Fe) and dibenzene metal sandwich structures 32 (especially dibenzenechromium 32, M=Cr) are well-known [5,14]. Heteroaromatic sandwich compounds of types 33 and 34 are also well-known [5,22], as well as three-decker complexes of phosphorus- (35) …”

Section: Complexes With Multi-centered Bonds (Cmb) [14]mentioning

confidence: 99%

“…Azole complexes 60 are being intensively studied [22]. As an example, we selected azomehine chelates, having, depending on donor atom (X), trans-(61) or cis-(62) structures [14,15].…”

Section: Molecular Complexesmentioning

confidence: 99%

“…In this respect, use of this route for syntheses of triphenylpyridine 77 (E = N), phosph -77 (E = P) and arseno -77 (E =As) benzene compounds seems attractive [14,22]. …”

Section: Molecular Complexesmentioning

confidence: 99%

“…Complexes of classic heterocycles, such as pyrrol 80 or pyridine 81, were obtained by exchange of the carbonyl ligand [22]. …”

Section: -Complexesmentioning

confidence: 99%

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Coordination Aspects in Modern Inorganic Chemistry

Garnovskii¹,

Sennikova²,

Kharisov³

2009

TOICJ

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Main types of coordination compounds in modern inorganic chemistry are discussed. Principal synthesis techniques for metal complexes and the problem of competitive coordination of ambident hard-soft ligands are discussed. A considerable attention is paid to polyfunctional materials, obtained on the basis of coordination compounds, especially molecular magnetics, organic light-emitting devices, and chemosensors.

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Section: Ementioning

confidence: 99%

Section: Complexes With Multi-centered Bonds (Cmb) [14]mentioning

confidence: 99%

“…Azole complexes 60 are being intensively studied [22]. As an example, we selected azomehine chelates, having, depending on donor atom (X), trans-(61) or cis-(62) structures [14,15].…”

Section: Molecular Complexesmentioning

confidence: 99%

“…In this respect, use of this route for syntheses of triphenylpyridine 77 (E = N), phosph -77 (E = P) and arseno -77 (E =As) benzene compounds seems attractive [14,22]. …”

Section: Molecular Complexesmentioning

confidence: 99%

“…Complexes of classic heterocycles, such as pyrrol 80 or pyridine 81, were obtained by exchange of the carbonyl ligand [22]. …”

Section: -Complexesmentioning

confidence: 99%

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Coordination Aspects in Modern Inorganic Chemistry

Garnovskii¹,

Sennikova²,

Kharisov³

2009

TOICJ

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Water &O‐Donor Ligands

Ogden

Beer

2005

Encyclopedia of Inorganic Chemistry

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The chemistry of a range of O‐donor ligands is described, with an emphasis on the various ligand coordination modes and different structural types of the complexes formed. Water as a ligand is discussed along with the related hydroxide and oxide species. The structure, preparation, and reactions of alkoxide and aryloxide complexes are described. Similar coverage is provided for the diketone ligands. The rich variety of coordination modes of oxoanions, carboxylates, and related ligands, is emphasized. Complexation and structural chemistry of macrocyclic O‐donor ligands are discussed, particularly focusing on crown ether and calixarene metal complexes. The final section provides an overview of the chemistry of other commonly encountered η 1 O‐donor ligands.

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