To apply ionization chambers to fusion fuel gas processing systems, high concentration tritium gas was experimentally measured with small volume 0.16 and 21.6 cm 3 ionization chambers. From plateau curves, the optimum electric field strength was obtained as 100-200 V /em. Detection efficiency was confirmed as dependent on the ionization ability of the filled gas, and moreover on its stopping power, because when the range of the {3-rays was shortened, the probability of energy loss by collisions with the electrode and chamber wall increased. Loss of ions by recombination was prevented by using a small volume ionization chamber. For example the 0.16 em• ionization chamber gave measurements with linearity to above 40% tritium gas. After the tritium gas measurements, the concentration levels inside the chamber were estimated from their memory currents. Although more than 1/4,000 of the maximum current was observed as a memory effect, the smaller ionization chamber gave a smaller memory effect.