Commercially available organolithium compounds as effective, simple precatalysts for silicon–nitrogen heterodehydrocoupling

Reuter, Matthew B.; Bushey, Claire E.; Javier-Jiménez, Diego R.; Waterman, Rory

doi:10.1039/d3dt02564k

Dalton Trans.

2023

DOI: 10.1039/d3dt02564k

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Commercially available organolithium compounds as effective, simple precatalysts for silicon–nitrogen heterodehydrocoupling

Matthew B. Reuter,

Claire E. Bushey,

Diego R. Javier-Jiménez

et al.

Abstract: A family of commercially available organolithium compounds were found to effectively catalyze the heterodehydrocoupling of silanes and amines under ambient conditions. Ubiquitous nBuLi (1) was utilized as the benchmark catalyst,...

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2024

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Cited by 3 publications

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Cobalt‐Driven Cross‐Dehydrocoupling of Silanes and Amines for Silylamine Synthesis

Szafoni,

Kuciński,

Hreczycho

2024

ChemCatChem

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Cobalt complexes featuring triazine‐based PNP ligands have proven to be exceptionally active and chemoselective pre‐catalysts in facilitating the dehydrogenative coupling between silanes and amines, leading to the synthesis of diverse aminosilanes. Notably, even challenging substrates exhibited high reactivity. The catalyst's unique feature of avoiding coupling with tertiary silanes enhances process chemoselectivity. It facilitates a more precise synthesis of silylamines possessing of SiH2–N and SiH–N motifs, overcoming challenges associated with broader reactivity seen in previous systems. In terms of its remarkable chemoselectivity, it is also noteworthy that the catalytic system exhibits both versatility and efficacy in converting substrates with untouched double and triple carbon‐carbon bonds. This accomplishment is particularly significant, given previous challenges brought about by the activity of commonly employed catalysts in the competitive hydrosilylation process.

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Cobalt‐Driven Cross‐Dehydrocoupling of Silanes and Amines for Silylamine Synthesis

Szafoni,

Kuciński,

Hreczycho

2024

ChemCatChem

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Recent progress of organosilicon compound: synthesis and applications

Mollabagher,

Mojtahedi,

Mousavi

2024

J IRAN CHEM SOC

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Grignard reagents as simple precatalysts for the dehydrocoupling of amines and silanes

Bushey,

Javier-Jiménez,

Reuter

et al. 2024

Dalton Trans.

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Commercially available organolithium compounds as effective, simple precatalysts for silicon–nitrogen heterodehydrocoupling

Abstract: A family of commercially available organolithium compounds were found to effectively catalyze the heterodehydrocoupling of silanes and amines under ambient conditions. Ubiquitous nBuLi (1) was utilized as the benchmark catalyst,...

Cited by 3 publications

References 50 publications

Cobalt‐Driven Cross‐Dehydrocoupling of Silanes and Amines for Silylamine Synthesis

Cobalt‐Driven Cross‐Dehydrocoupling of Silanes and Amines for Silylamine Synthesis

Recent progress of organosilicon compound: synthesis and applications

Grignard reagents as simple precatalysts for the dehydrocoupling of amines and silanes

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