The transition amplitude for electron-positron annihilation
during positron-hydrogen scattering is formulated in terms of
the half-shell T-matrix elements obtained from a solution of
the momentum space Lippmann-Schwinger equation. The derived
expression is well defined at energies below the positronium (Ps)
formation threshold. However, singularities in the transition
amplitude exist at energies above the Ps-formation threshold.
The annihilation parameter for positron-hydrogen scattering is
computed in a variety of models at energies below the
Ps-formation threshold. Calculations with the largest basis
reproduce previous variational calculations of ZJeff for
the J = 0 and 1 partial waves. Accurate values of
ZJeff were also given for the J = 2, 3 and 4 partial
waves to give a summed Zeff that is probably the most
accurate so far reported.