2013
DOI: 10.1039/c2cy20645e
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Combustion synthesis of LaMn1−xAlxO3+δ (0 ≤ x ≤ 1): tuning catalytic properties for methane deep oxidation

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Cited by 33 publications
(11 citation statements)
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References 56 publications
(92 reference statements)
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“…Since coking is less likely to occur under oxygen-rich environments, agglomeration of catalyst particle and/or deconstruction of perovskite structure should be responsible for catalyst deactivation. 64 The SEM micrographs of freshly prepared and used LaMn 1Ày Ni y O 3 aer on-stream testing (see Fig. S7 of ESI †) further supported this claim: some welding and particle agglomeration could be identied on used samples; however, no carbon deposition (e.g., carbon nanotubes) was specied.…”
Section: Resultsmentioning
confidence: 70%
“…Since coking is less likely to occur under oxygen-rich environments, agglomeration of catalyst particle and/or deconstruction of perovskite structure should be responsible for catalyst deactivation. 64 The SEM micrographs of freshly prepared and used LaMn 1Ày Ni y O 3 aer on-stream testing (see Fig. S7 of ESI †) further supported this claim: some welding and particle agglomeration could be identied on used samples; however, no carbon deposition (e.g., carbon nanotubes) was specied.…”
Section: Resultsmentioning
confidence: 70%
“…In addition, the mean grain sizes of the samples were estimated using the Debye-Scherrer equation. The crystallite size of LM-5 is 16.8 nm, which is much smaller than other LaMnO 3 , 23,24 suggesting that carbon sphere template method can greatly reduce the crystallite size. The EDX images of LM-1 to LM-6 are shown in Fig.…”
Section: Resultsmentioning
confidence: 88%
“…520 • C and increases with the Al content. Notably, the T 50 value decreases with the increase of the SSA, the highest SSA (22 m 2 /g) corresponding to the La(Mn 0.9 Al 0.1 )O 3 system [250]. Recently, Miao et al [251] reported a catalyst based on La(Mn,Fe)O 3 with an excellent stability at 550 • C in the catalytic combustion of methane.…”
Section: Catalytic Combustion Of Methanementioning
confidence: 99%