“…For instance, in-cylinder IC-engine gas-phase emission has been used to study ignition and combustion processes, air-to-fuel ratio (AFR) transients and distributions, knock, and combustion control [ 41 , 42 , 43 , 44 , 45 , 46 , 47 ]. Transient gas emission measurements using spectrally broad (~200–650 nm) integration can have a bimodal temporal shape, with the initial mode arising from flame-front emission and the second mode due to emission from the burned-gas region behind the flame front [ 43 , 45 ]. The flame-front emission sweeps through the optical sampling field first; the burned-gas emission signal follows and can be larger due to its greater spatial extent and more extensive overlap with the optical field of view, while in other cases, reactions controlling the burned-gas emission can be quenched by relatively cool cylinder surfaces [ 43 , 45 ].…”