Carbon nanotubes (CNTs) possess unique electronic, mechanical, and structural properties. They were shown to be effective and stable low temperature adsorbent materials that could make them potentially useful for gas storage and separation of various gas mixtures. Carbon dioxide (CO 2 is a greenhouse gas and CO 2 levels in the atmosphere have been steadily increasing due to human activity. Hence, capturing CO 2 is an active research area. Previous studies on CO 2 adsorption using CNTs focused on low concentration CO 2 environments; however, capturing CO 2 at the source (coal plants, automobile emissions, etc.) is a more realistic solution, therefore, in the current study, the potential use of CNTs as CO 2 adsorbents at high concentration CO 2 environments is reported. The effects of single walled carbon nanotube diameter and length, and CO 2 concentration were studied using molecular dynamics simulations at 300 and 320 K. Results showed that CO 2 molecules were selectively adsorbed by the single walled carbon nanotubes (SWNTs), and adsorption was dependent on both the internal volume of the nanotube and the cross-sectional area of the tube entrance. Temperature increase had a substantial impact on the location of CO 2 molecules in and around the nanotube, i.e., at 300 K, CO 2 molecules were located both inside and on the nanotube surface; whereas at 320 K, the CO 2 molecules were mostly inside the nanotube. This result suggests that the mechanism of CO 2 adsorption and retention can be controlled by temperature. Finally, our results showed that although the amount of adsorbed CO 2 increased with increasing CO 2 concentration, the efficiency of adsorption increased with decreasing CO 2 concentration.