Abstract:The
reactivity of sulfur- and selenium-centered nucleophiles toward
1-naphthyl radicals was studied in dimethylsulfoxide. The photostimulated
reaction of sulfide anions, –SC(NH)C6H5 (1), –SC(NH)NH2 (2), and –SC(NH)CH3 (3), renders, after the addition of MeI, methyl 1-naphthylsulfide
as a main product together with bis(1-naphthyl) sulfide and naphthalene
under irradiation. Concordantly, the reaction of selenide anions, –SeC(NH)C6H5 (4), –SeC(NH)NH2 (5), and –SeCN (6), produces methyl 1-naphthyl selen… Show more
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