“…A secondary excitation of the laser-induced plasma can enhance the optical signals and improve the detection sensitivity. Techniques employed for secondary excitation in LIBS include double laser pulses (St-Onge et al , 1998;Babushok et al , 2006;Ctvrtn í kova et al , 2008;Windom and Hahn, 2009;Viskup et al , 2010;Heilbrunner et al , 2012), electric spark discharges (Chen et al , 2010;Kexue et al , 2010), and radiofrequency (Bian et al , 2005;Deng et al , 2010;Pedarnig et al , 2011) and microwave (Ikeda et al , 2010;Liu et al , 2010) radiation. …”