Combination of Resonance and Non‐Resonance Chiral Raman Scattering in a Cobalt(III) Complex
Qin Yang,
Julien Bloino,
Hana Šestáková
et al.
Abstract:Resonance Raman optical activity (RROA) spectra with high sensitivity reveal details on molecular structure, chirality, and excited electronic properties. Despite the difficulty of the measurements, the recorded data for the Co(III) complex with S,S‐N,N‐ethylenediaminedisuccinic acid are of exceptional quality and, coupled with the theory, spectacularly document the molecular behavior in resonance. This includes a huge enhancement of the chiral scattering, contribution of the antisymmetric polarizabilities to … Show more
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