2008
DOI: 10.1051/0004-6361:200810717
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Collisional excitation of water in warm astrophysical media

Abstract: Context. The interpretation of water line emission from infrared and submillimetre observations requires a detailed knowledge of collisional rate coefficients over a wide range of levels and temperatures. Aims. We attempt to determine rotational and rovibrational rate coefficients for H 2 O colliding with both H 2 and electrons in warm, molecular gas. Methods. Pure rotational rates are derived by extrapolating published data using a new method partly based on the information (phase space) theory of Levine and … Show more

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Cited by 94 publications
(125 citation statements)
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“…This model does not intend to fit any particular object. A large non-LTE H 2 O ro-vibrational model calculation was included to consistently calculate the Spitzer as well as the Herschel H 2 O emission lines by applying escape probability theory (Faure et al 2004(Faure et al , 2007Faure & Josselin 2008). At ∼3 AU, the gas densities are high enough to excite the 63.32 μm o-H 2 O line and the dust temperature close to the mid-plane is low enough for H 2 O to freeze onto grains.…”
Section: Resultsmentioning
confidence: 99%
“…This model does not intend to fit any particular object. A large non-LTE H 2 O ro-vibrational model calculation was included to consistently calculate the Spitzer as well as the Herschel H 2 O emission lines by applying escape probability theory (Faure et al 2004(Faure et al , 2007Faure & Josselin 2008). At ∼3 AU, the gas densities are high enough to excite the 63.32 μm o-H 2 O line and the dust temperature close to the mid-plane is low enough for H 2 O to freeze onto grains.…”
Section: Resultsmentioning
confidence: 99%
“…The rotational rate coefficients used here are based on the results of Green et al (1993), as are those of Neufeld & Kaufman (1993). Faure & Josselin (2008) recently calculated new rotational rates and compared them to those of Neufeld & Kaufman (1993), finding higher cooling rates for temperatures < ∼ 1500 K and lower cooling rates for temperatures > ∼ 1500 K. They also found that the rotational rate coefficients can be uncertain by factors of a few up to an order of magnitude, which is reflected in the uncertainties on the cooling rates.…”
Section: Gas Kinetic Temperature: Inmentioning
confidence: 99%
“…Within these files, one for each spin species of H2O, additional comment lines credit the energy level data to Tennyson et al (2001) and the Einstein A-values to Barber et al (2006). Collisional data is divided between two collisional partners: H2 molecules and free electrons (Faure & Josselin 2008).…”
Section: Molecular Datamentioning
confidence: 99%
“…Collision data for both spin species of H2O and molecular hydrogen do not specify the spin species of H2 used; in fact they are an average of ortho-and para-H2 contributions, assuming the thermal abundance ratio of 3 o-H2 to 1 p-H2. This is considered adequate for temperatures above 200 K (the lowest tabulated by Faure & Josselin 2008). The effect of changing sets of rate coefficients in numerical calculations has been considered by Daniel & Cernicharo (2013), who concluded that, in models of H2O masers, the likely uncertainty introduced into maser optical depths is a factor of 2 in the worst cases.…”
Section: Molecular Datamentioning
confidence: 99%