Chinese learning materials for children has yet to be explored. This study revises the assessment form in Chinese Learning Materials Design Prerequisites, developed by Wang in 2008, to evaluate Chinese learning materials for Children, with a focus on a book series entitled Children’s Chinese Reader published by the Overseas Community Affairs Council in Taipei, Taiwan. The purpose of this study is two-fold. The first attempt is to find out the potential merits and the drawbacks that need addressing urgently. The second attempt is to see the potentiality of using the same materials on different groups of children leaners such as children learning Chinese as a second language, instead of the target learners that the book series has set on. The finding from the initial evaluation indicated a low score of 91 in individually evaluated categories except one, which is being systematic. Categories in being specific, being practical, being scientific, and being intriguing all received a low score. The current surmise is that the then Children’s Chinese Reader is a synchronic product of its time that now calls for advancement in latest theoretical research and contemporary teaching principles if materials for children’s learning can play an appropriate role in modern-day teaching.