Cold reactions of He<sup>+</sup> with OCS and CO<sub>2</sub>: competitive kinetics and the effects of the molecular multipole moments

Martins, Fernanda B. V.; Zhelyazkova, Valentina; Merkt, Frédéric

doi:10.1039/d4cp02871f

Phys. Chem. Chem. Phys.

2024

DOI: 10.1039/d4cp02871f

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Cold reactions of He⁺ with OCS and CO₂: competitive kinetics and the effects of the molecular multipole moments

Fernanda B. V. Martins,

Valentina Zhelyazkova,

Frédéric Merkt

Abstract: The reactions of He+ with OCS and CO2 were studied at collision energies between 0.2 and 30 K ⋅ kB by merging a beam of Rydberg He atoms with rotationally cold seeded supersonic expansions containing either OCS or 13CO2 or a mixture of OCS and 13CO2.

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Cold reactions of He⁺ with OCS and CO₂: competitive kinetics and the effects of the molecular multipole moments

Abstract: The reactions of He+ with OCS and CO2 were studied at collision energies between 0.2 and 30 K ⋅ kB by merging a beam of Rydberg He atoms with rotationally cold seeded supersonic expansions containing either OCS or 13CO2 or a mixture of OCS and 13CO2.

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References 67 publications

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Cold reactions of He+ with OCS and CO2: competitive kinetics and the effects of the molecular multipole moments

Abstract: The reactions of He+ with OCS and CO2 were studied at collision energies between 0.2 and 30 K ⋅ kB by merging a beam of Rydberg He atoms with rotationally cold seeded supersonic expansions containing either OCS or 13CO2 or a mixture of OCS and 13CO2.

Cited by 0 publications

References 67 publications

No citations

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Cold reactions of He⁺ with OCS and CO₂: competitive kinetics and the effects of the molecular multipole moments