Abstract:Aryl-corrins is a class of B 12 derivatives that embodies "antivitamin" properties and represents a biologically important class of compounds that hence demands investigation. In our previous study, we experimentally determined bond strength in a series of aryl-corrins by the threshold CID experiments and compared these BDE's with those calculated with DFT. [1] We found that the computed BDEs were very much dependent on the chosen structure. Given that aryl-cobinamides have many side chains that increase their… Show more
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