Analytically exact solutions of a driven two-level system are extremely important to many areas of physics (E. Barnes and S. Das Sarma, Phys. Rev. Lett. 109, 060401, 2012), we here present a simple method of synchronous and asynchronous combined-modulations to generate a lot of new exact solutions, and apply the simplest several solutions to perform the coherent control of quantum states. The physical interesting phenomena such as the arbitrary population transfers between the different and/or asymptotic stationary states and the controlled coherent population oscillation are achieved analytically and numerically. Simplicities of the exact solutions and the modulated fields render the control strategies more transparent and the qubit manipulation more convenient in experiments.