Cocondensation reactions of heterocyclic aromatic compounds with lithium, calcium and magnesium atoms at 77K

Reaction Chemistry of Solid-State Pyridine Thin Films with Vapor Deposited Ag, Mg, and Al

“…13,19 For Mg, these studies have focused predominantly on interactions occurring in isolated 1:1 Mg + :pyridine conjugates, although one study of co-condensed Mg and pyridine was reported in which bipyridyl was identified as a reaction product. 35 The reaction chemistry between Al and pyridine has been given the least attention to date, with only one gas phase 11 and one theoretical 4 study of Al + -pyridine conjugates reported.…”

Colloidal calcium nanoparticles: digestive ripening in the presence of a capping agent and coalescence of particles under an electron beam

“…Although Mendoza and Tacke reported the formation of (C 4 H 3 O)CaH via C-H bond activation within furan, the hydride species has not been well characterized. 18 The powder XRD of the sample showed peaks for both Ca(0) (FCC) and CaH 2 (orthorhombic), we found no hydride particles in the TEM studies. This suggests that CaH 2 is present in the bulk state together with Ca nanoparticles.…”

Synthetic Techniques and Applications of Activated Nanostructurized Metals: Highlights up to 2008

“…Nowadays, cryochemical procedures are applied for obtaining metal-polymer materials (by low-temperature cocondensation of metal and monomer vapors followed by low-temperature solid-state polymerization of the cocondensate under irradiation) [42][43][44][45] and various metal complexes, for instance isomeric complexes [Ni( 3 -PC 2 Bu t 2 )( 5 -P 3 C 2 t Bu 2 )] and [Ni( 4 -P 2 C 2 Bu t 2 ) 2 ] (by the reaction of nickel atoms with t BuCP) [46], In(P 3 C 2 Bu' 2 ) [47], zerovalent bis( -arene)lanthanide complexes of the form [Ln( 6 -C 6 H 3 -t Bu 3 -1,3,5) 2 ] (by codeposition of a monatomic lanthanide vapor (Sm, Eu, Tm or Yb) and tri-tert-butylbenzene C 6 H 3 -t Bu 3 -1,3,5 onto a cold (77 K) surface) [48], and others [49][50][51]. Low temperature surface chemistry and nanostructures are reviewed in [52].…”