Cobalt(II)-porphyrin catalyzed selective functionalization of alkanes with sulfurylchloride: A remarkable substituent effect

Khanna, Vibha; Tamilselvan, Pitchiah; Kalra, Swinder Jeet Singh; Iqbal, Javed

doi:10.1016/s0040-4039(00)78223-2

Cited by 8 publications

(1 citation statement)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…An interesting variation on an alkane functionalization reaction was observed in a cobalt(II) porphyrin complex. 32 Depending on ligand choice, these cobalt catalysts were effective in either the chlorination or sulfochlorination of alkane substrates in good yields. The reaction is simply performed by combining the alkane, sulfuryl chloride and the catalyst and heating to 85 uC.…”

Section: Future Prospects In Polyolefin Modificationmentioning

confidence: 99%

Post-polymerization functionalization of polyolefins

2005

View full text Add to dashboard Cite

Polyolefins are macromolecular alkanes and include the most familiar and most commercially produced plastic, polyethylene. The low cost of these materials combined with their diverse and desirable property profiles drive such large-scale production. One property that renders polyolefins so attractive is their resistance to harsh chemical environments. However, this attribute becomes a severe limitation when attempting to chemically convert these plastics into value-added materials. Functionalization of polymers is a useful methodology for the generation of new materials with wide ranging applications, and this tutorial review describes both new and established methods for the post-polymerization modification of polyolefins.

show abstract

Section: Future Prospects In Polyolefin Modificationmentioning

confidence: 99%

Post-polymerization functionalization of polyolefins

2005

View full text Add to dashboard Cite

show abstract

Halogenation of Hydrocarbons

Larock

Zhang

2018

Comprehensive Organic Transformations

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: Cobalt(II)‐Porphyrin Catalyzed Selective Functionalization of Alkanes with Sulfuryl Chloride: A Remarkable Substituent Effect.

et al. 1994

View full text Add to dashboard Cite

1994 substitution reactions substitution reactions O 0040 52 -048 Cobalt(II)-Porphyrin Catalyzed Selective Functionalization of Alkanes with Sulfuryl Chloride: A Remarkable Substituent Effect. -Alkanes react with sulfuryl chloride in the presence of cobalt(II)-porphyrin (Ia) to yield the corresponding chlorides. In the presence of catalyst (Ib) a remarkable change in chemoselectivity is observed. -(KHANNA, V.; TAMILSELVAN, P.; KALRA, S. J. S.; IQBAL, J.; Tetrahedron Lett. 35 (1994) 32, 5935-5938; Dep. Chem., Indian Inst. Technol., Kanpur 208 016, India; EN)

show abstract

Cobalt(II)-porphyrin catalyzed selective functionalization of alkanes with sulfurylchloride: A remarkable substituent effect

Cited by 8 publications

References 6 publications

Post-polymerization functionalization of polyolefins

Post-polymerization functionalization of polyolefins

Halogenation of Hydrocarbons

ChemInform Abstract: Cobalt(II)‐Porphyrin Catalyzed Selective Functionalization of Alkanes with Sulfuryl Chloride: A Remarkable Substituent Effect.

Contact Info

Product

Resources

About