Cobalt-Catalyzed Regiodivergent Heck-Type Reaction of Simple Unactivated Alkenes
Chunyang Zhao,
Chao Dong,
Wenxuan Ma
et al.
Abstract:Regiocontrol has been a long-standing challenge in the Heck-type reaction of unactivated alkenes due to the presence of multiple detachable β-hydrogens, but it also represents an intriguing research topic owing to the potential for accessing structurally diverse internal aliphatic alkenes. Herein, a cobaltcatalyzed regiodivergent Heck-type reaction of simple unactivated alkenes and fluoroalkyl bromides is reported, yielding a variety of internal aliphatic olefins containing biologically relevant fluorinated mo… Show more
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